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Quantitative structural determination of the high coverage phase of the benzoate species on Cu(110)

Pascal, M., Lamont, C.L.A., Kittel, M., Hoeft, J.T., Terborg, R., Polcik, M., Kang, J.H., Toomes, R.L. and Woodruff, D.P. (2001) Quantitative structural determination of the high coverage phase of the benzoate species on Cu(110). Surface Science, 492. pp. 285-293. ISSN 0039-6028

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Abstract

The local adsorption site and molecular orientation of the benzoate species adsorbed on Cu(1 1 0) at 330 K have been determined using O1s scanned-energy mode photoelectron diffraction. The molecule was found to interact with the surface via the carboxylate group, giving a Cu–O bond length of 1.91 Å. The molecules occupy the short bridge sites (the O atoms being slightly displaced from atop sites) and are aligned along the [ 1 0] azimuth with the molecular plane oriented perpendicular to the surface

Item Type: Article
Additional Information: Copyright © 2007 Elsevier B.V. All rights reserved. ScienceDirect® is a registered trademark of Elsevier B.V.
Subjects: Q Science > QD Chemistry
Schools: School of Applied Sciences
School of Applied Sciences > Materials and Catalysis Research Centre
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Depositing User: Briony Heyhoe
Date Deposited: 13 Jul 2007
Last Modified: 28 Jul 2010 18:20
URI: http://eprints.hud.ac.uk/id/eprint/248

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