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Construction of β-Haloenamides via Direct Copper-Promoted Coupling of Lactams with 2-Chloro and 2-Bromo Vinyliodides.

Sun, Cuixiang, Camp, Jason and Weinreb, Steven M. (2006) Construction of β-Haloenamides via Direct Copper-Promoted Coupling of Lactams with 2-Chloro and 2-Bromo Vinyliodides. Organic Letters, 8 (9). pp. 1779-1781. ISSN 1523-7060

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Abstract

Cu(I)-catalyzed coupling of lactams with (E)-2-chlorovinyl iodides or (E)-2-bromovinyl iodides produces the corresponding β-halo enamides in moderate to excellent yields. E.g., in the presence of CuI and MeNHCH2CH2NHMe, coupling of (E)-2-chlorovinyl iodide I with lactam II gave 43% β-halo enamide III. [on SciFinder(R)]

Item Type: Article
Additional Information: Unmapped bibliographic data: PY - 2006/// [EPrints field already has value set] M3 - 10.1021/ol060093a [Field not mapped to EPrints] JA - Org. Lett. [Field not mapped to EPrints]
Uncontrolled Keywords: halo enamide prepn, copper catalyst coupling lactam chlorovinyl bromovinyl iodide
Subjects: Q Science > Q Science (General)
Q Science > QD Chemistry
Schools: School of Applied Sciences
Related URLs:
Depositing User: Sara Taylor
Date Deposited: 13 Nov 2014 16:59
Last Modified: 13 Nov 2014 16:59
URI: http://eprints.hud.ac.uk/id/eprint/22279

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