Search:
Computing and Library Services - delivering an inspiring information environment

Synthesis of Highly Substituted Pyrroles via Nucleophilic Catalysis.

Ngwerume, Simbarashe and Camp, Jason (2010) Synthesis of Highly Substituted Pyrroles via Nucleophilic Catalysis. Journal of Organic Chemistry, 75 (18). pp. 6271-6274. ISSN 0022-3263

Metadata only available from this repository.

Abstract

A nucleophilic catalysis method providing a concise synthesis of di-, tri-, and tetrasubstituted pyrroles is described. This regioselective one-pot method relies on nucleophilic catalysis of the intermol. addn. of oximes to activated alkynes and thermal rearrangement of the in situ generated O-vinyl oximes to form pyrroles that contain a functional group handle at the C3/C4 position. [on SciFinder(R)]

Item Type: Article
Additional Information: Unmapped bibliographic data: PY - 2010/// [EPrints field already has value set] M3 - 10.1021/jo1011448 [Field not mapped to EPrints] JA - J. Org. Chem. [Field not mapped to EPrints]
Uncontrolled Keywords: oxime stereoselective prepn, ketone hydroxyamine hydrochloride diastereoselective condensation, pyrrole prepn, alkyne oxime regioselective intermol addn nucleophilic catalysis, vinyl oxime thermal rearrangement microwave irradn
Subjects: Q Science > Q Science (General)
Q Science > QD Chemistry
Schools: School of Applied Sciences
Related URLs:
Depositing User: Sara Taylor
Date Deposited: 13 Nov 2014 16:46
Last Modified: 13 Nov 2014 16:46
URI: http://eprints.hud.ac.uk/id/eprint/22277

Downloads

Downloads per month over past year

Repository Staff Only: item control page

View Item View Item

University of Huddersfield, Queensgate, Huddersfield, HD1 3DH Copyright and Disclaimer All rights reserved ©