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Multifaceted catalysis approach to nitrile activation: direct synthesis of halogenated allyl amides from allylic alcohols.

Lester, Roy P., Dunsford, Jay J. and Camp, Jason (2013) Multifaceted catalysis approach to nitrile activation: direct synthesis of halogenated allyl amides from allylic alcohols. Organic & Biomolecular Chemistry, 11 (43). pp. 7472-7476. ISSN 1477-0520

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Abstract

Allyl amides were synthesized from the reaction of allyl alcs. and halogenated nitriles using a platinum multifaceted catalysis approach in which both the nucleophilic addn. and subsequent [3,3]-sigmatropic rearrangement steps of the process were catalyzed by the same complex. Addnl., 1H/13C{1H} NMR and GC studies provided the first insights into the mechanism of this transformation. [on SciFinder(R)]

Item Type: Article
Additional Information: Unmapped bibliographic data: PY - 2013/// [EPrints field already has value set] M3 - 10.1039/c3ob41692e [Field not mapped to EPrints] JA - Org. Biomol. Chem. [Field not mapped to EPrints]
Uncontrolled Keywords: halogenated nitrile allyl alc nucleophilic addn sigmatropic rearrangement mechanism, allyl amide halogenated prepn multifaceted platinum catalyst
Subjects: Q Science > Q Science (General)
Q Science > QD Chemistry
Schools: School of Applied Sciences
Related URLs:
Depositing User: Sara Taylor
Date Deposited: 13 Nov 2014 09:57
Last Modified: 13 Nov 2014 09:57
URI: http://eprints.hud.ac.uk/id/eprint/22269

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