Search:
Computing and Library Services - delivering an inspiring information environment

Tricarbonylchlorido(6'7'-dihydro-5’H-spiro[cyclopentane-1,6'-dipyrido-[3,2-d:2',3'-f][1,3]diazepine]-κ2N1,N11)-rhenium(I)

Clegg, Oliver R., Harding, Lindsay P., Miller, John W. and Rice, Craig R. (2013) Tricarbonylchlorido(6'7'-dihydro-5’H-spiro[cyclopentane-1,6'-dipyrido-[3,2-d:2',3'-f][1,3]diazepine]-κ2N1,N11)-rhenium(I). Acta Crystallographica Section E, 69 (10). m526. ISSN 1600-5368

[img]
Preview
PDF - Published Version
Download (287kB) | Preview

Abstract

In the title compound, [ReCl(C15H16N4)(CO)3], the ReI ion is coordinated in a distorted octahedral geometry by one Cl atom, two N atoms of the bidentate ligand and three carbonyl groups. The cyclopentane group is orientated in a transoid fashion with respect to the chloride ligand. The dihedral angle between the pryridine rings is 10.91 (12)°. In the crystal, N-H...Cl hydrogen bonds link complex molecules, forming a two-dimensional network parallel to (001).

Item Type: Article
Subjects: Q Science > QD Chemistry
Schools: School of Applied Sciences
Related URLs:
Depositing User: Lindsay Harding
Date Deposited: 17 Jul 2014 15:58
Last Modified: 02 Dec 2016 18:25
URI: http://eprints.hud.ac.uk/id/eprint/21239

Downloads

Downloads per month over past year

Repository Staff Only: item control page

View Item View Item

University of Huddersfield, Queensgate, Huddersfield, HD1 3DH Copyright and Disclaimer All rights reserved ©