Search:
Computing and Library Services - delivering an inspiring information environment

Improving alkynyl(aryl)iodonium salts: 2-anisyl as a superior aryl group

Hamnett, David J. and Moran, Wesley J. (2014) Improving alkynyl(aryl)iodonium salts: 2-anisyl as a superior aryl group. Organic & Biomolecular Chemistry, 12. pp. 4156-4162. ISSN 1477-0520

[img] PDF - Published Version
Available under License Creative Commons Attribution.

Download (615kB)

Abstract

The majority of alkynyl(aryl)iodonium salts reported in the literature are derived from iodobenzene. This article describes the effects of varying this iodoarene building block on the synthesis, reactivity and stability of these salts. Two procedures to synthesize a variety of known and novel alkynyl(aryl)iodonium tosylates directly from the iodoarene are reported. In the reactions of these salts, those derived from 2-iodoanisole gave superior results than the others tested in every reaction. Isothermal microcalorimetry indicated that these novel salts were significantly more stable and less prone to decomposition than all of the other derivatives.

Item Type: Article
Subjects: Q Science > QD Chemistry
Schools: School of Applied Sciences
Related URLs:
Depositing User: Graham Stone
Date Deposited: 23 May 2014 15:22
Last Modified: 25 Aug 2016 17:34
URI: http://eprints.hud.ac.uk/id/eprint/20364

Downloads

Downloads per month over past year

Repository Staff Only: item control page

View Item View Item

University of Huddersfield, Queensgate, Huddersfield, HD1 3DH Copyright and Disclaimer All rights reserved ©