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Charrier, E., Charsley, Edward L., Markham, H.M., Berger, B. and Griffiths, Trevor T. (2006) Determination of the temperature and enthalpy of the solid-solid phase transition of caesium nitrate by differential scanning calorimetry. Thermochimica Acta, 445. pp. 36-39. ISSN 0040-6031
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Abstract
The equilibrium temperature of the solid–solid phase transition of high purity caesium nitrate has been measured accurately by stepwise heating and by the extrapolation to zero heating rate method. A mean value of 154.3 ± 0.1 °C was obtained using two different heat flux DSC instruments. A value of 3.44 ± 0.04 kJ mol−1 was determined for the enthalpy of transition.
| Item Type: | Article |
|---|---|
| Additional Information: | Copyright © 2007 Elsevier B.V. All rights reserved. ScienceDirect® is a registered trademark of Elsevier B.V. |
| Subjects: | Q Science > QD Chemistry |
| Schools: | School of Applied Sciences School of Applied Sciences > Materials and Catalysis Research Centre |
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| References: | [1] B. Berger, S.D. Brown, E.L. Charsley, J.J. Rooney, R.P. Claridge and T.T. Griffiths, Proceedings of the 29th International Pyrotechnics Seminar IPSUSA (2002), p. 743. [2] P.W. Bridgeman, Proc. An. Acad. 51 (1916), p. 581. [3] A. Mustajoki, An. Acad. Sci. Fennicae 6 (1957), p. 1. [4] M. Bakes, J. Guion and J. Dupuis, C. R. Acad. Sci. 256 (1963), p. 2376. [5] D.I. Marchidan and L. Vasu, Rev. Roumaine de Chimie 18 (1973), p. 1295. [6] M.J. Maeso and J. Largo, Thermochim. Acta 222 (1993), p. 195. Abstract | Abstract + References | PDF (363 K) [7] T. Jriri, J. Rogez, C. Bergman and J.J. Mathieu, Thermochim. Acta 266 (1995), p. 147. SummaryPlus | Full Text + Links | PDF (790 K) [8] H. Preston-Thomas, Metrologia 27 (1990), pp. 3–10. Full Text via CrossRef | View Record in Scopus | Cited By in Scopus [9] G.W.H. Höhne, H.K. Cammenga, W. Eysel, E. Gmelin and W. Hemminger, Thermochim. Acta 160 (1990), p. 1. Abstract | Abstract + References | PDF (637 K) [10] M.J. Richardson In: K.D. Maglic, A. Cezairliyan and V.E. Peletsky, Editors, Compendium of Thermophysical Property Measurement Methods, Plenum Press, New York (1992), p. 519. [11] E. L. Charsley, P. G. Laye, V. Palakollu, J. J. Rooney , B. Joseph, Thermochim. Acta, in press. [12] F. Grønvold, J. Therm. Anal. 13 (1978), p. 419. |
| Depositing User: | Briony Heyhoe |
| Date Deposited: | 12 Jul 2007 |
| Last Modified: | 08 Sep 2010 13:47 |
| URI: | http://eprints.hud.ac.uk/id/eprint/202 |
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