Search:
Computing and Library Services - delivering an inspiring information environment

Synthesis and Characterisation of Diruthenium Paddlewheel Compounds Bearing 2,6-Di(p-tolyl)benzoate Ligands

Gracia, Raquel and Patmore, Nathan J. (2010) Synthesis and Characterisation of Diruthenium Paddlewheel Compounds Bearing 2,6-Di(p-tolyl)benzoate Ligands. Journal of Cluster Science, 21 (3). pp. 339-350. ISSN 1040-7278

Metadata only available from this repository.

Abstract

The mixed carboxylate diruthenium complexes trans-[Ru 2 II,III (O2CCH3)2(O2CAr)2Cl] (I) and trans-[Ru 2 II,II (O2CCH3)2(O2CAr)2] (II) (O2CAr = 2,6-di(p-tolyl)benzoate) have been synthesised along with [Ru 2 II,III (O2CAr)4Cl] (III) and the homoleptic complex [Ru 2 II,II (O2CAr)4] (IV). The structures trans-[Ru2(O2CCH3)2(O2CAr)2Cl(thf)]·(thf) and [Ru2(O2CAr)4Cl(η 1-CH2Cl2)] were determined by X-ray crystallography, and display the expected paddlewheel arrangement of the carboxylate ligands around the diruthenium core. The structure of III is a rare example of a structurally characterised dichloromethane complex, highlighting the Lewis acidic nature of the diruthenium axial position. The bulky −O2CAr ligand protects the axial positions from intermolecular interactions in the absence of strong nucleophiles for III and IV, and the effect this has on the electronic structure of the diruthenium core in these complexes was investigated by cyclic voltammetry, electronic absorption spectroscopy and magnetic susceptibility studies.

Item Type: Article
Subjects: Q Science > Q Science (General)
Q Science > QD Chemistry
Schools: School of Applied Sciences
Related URLs:
Depositing User: Sharon Beastall
Date Deposited: 02 Apr 2014 11:36
Last Modified: 02 Apr 2014 11:36
URI: http://eprints.hud.ac.uk/id/eprint/19952

Downloads

Downloads per month over past year

Repository Staff Only: item control page

View Item View Item

University of Huddersfield, Queensgate, Huddersfield, HD1 3DH Copyright and Disclaimer All rights reserved ©