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Photochemical ligand ejection from non-sterically promoted Ru(ii)bis(diimine) 4,4′-bi-1,2,3-triazolyl complexes

Welby, Christine E., Armitage, Georgina K., Bartley, Harry, Sinopoli, Alessandro, Uppal, Baljinder S. and Elliott, Paul I. (2014) Photochemical ligand ejection from non-sterically promoted Ru(ii)bis(diimine) 4,4′-bi-1,2,3-triazolyl complexes. Photochemical & Photobiological Sciences. ISSN 1474-905X

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Abstract

Complexes of the form [Ru(diimine)2(btz)]2+ (btz = 1,1′-dibenzyl-4,4′-bi-1,2,3-triazolyl) are observed to undergo photochemical ejection of the btz ligand in the absence of any promotion through steric congestion to generate cis-bis(solvent) complexes [Ru(diimine)2(solvent)2]2+.

Graphical abstract: Photochemical ligand ejection from non-sterically promoted Ru(ii)bis(diimine) 4,4′-bi-1,2,3-triazolyl complexes

Item Type: Article
Subjects: Q Science > Q Science (General)
Schools: School of Applied Sciences
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Depositing User: Cherry Edmunds
Date Deposited: 02 Apr 2014 09:25
Last Modified: 02 Dec 2016 05:19
URI: http://eprints.hud.ac.uk/id/eprint/19934

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