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Reactions of tertiary propargyl alcohols with sodium halides under oxidative conditions

Aborways, Marwa M. and Moran, Wesley J. (2014) Reactions of tertiary propargyl alcohols with sodium halides under oxidative conditions. Tetrahedron Letters, 55 (13). pp. 2127-2129. ISSN 0040-4039

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Abstract

The study of the reactions of tertiary propargyl alcohols with sodium halides under oxidative conditions is presented. With sodium iodide, α-iodoenones were formed, however, with sodium bromide or chloride the α-haloenones were only formed in low yields under anhydrous conditions. Conversely, upon addition of water to the reaction mixtures, α,α-dibromoketones and α,α-dichloroketones were formed in good yields, but α,α-diiodoketones were not observed

Item Type: Article
Subjects: Q Science > QD Chemistry
Schools: School of Applied Sciences
Related URLs:
Depositing User: Wesley Moran
Date Deposited: 27 Mar 2014 14:59
Last Modified: 18 Aug 2016 15:47
URI: http://eprints.hud.ac.uk/id/eprint/19887

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