Aiken, Stuart, Gabbutt, Christopher D., Gillie, Lisa .J., Heywood, Jonathan, Jacquemin, Denis, Rice, Craig R. and Heron, B. Mark (2013) The Remarkable Hyperchromicity of Ketohydrazone Dyes and Pigment Lakes Derived from 4-Morpholino-2-naphthol. European Journal of Organic Chemistry, 2013 (36). pp. 8097-8107. ISSN 1434-193XMetadata only available from this repository.
The syntheses of a series of new ketohydrazone dyes and pigment lakes with a unique structural motif derived from 4-morpholino-2-naphthol are described. The morpholine substituent is responsible for the hypsochromically shifted absorption maxima with significantly enhanced molar extinction coefficients of the new dyes; this conclusion is supported by time-dependent DFT (TD-DFT) simulations. The location of the morpholine substituent at a sterically demanding site in the pigment lake obstructs further coordination of the bridging sulfonate groups in the solid state and prevents the formation of a 1-dimensional polymeric system, which is common for other pigment lakes.
|Subjects:||Q Science > QD Chemistry|
|Schools:||School of Applied Sciences|
|Depositing User:||Mark Heron|
|Date Deposited:||07 Nov 2013 16:42|
|Last Modified:||05 Mar 2014 13:40|
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