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Relationship between metal–metal bond length and internal rotation in diruthenium tetracarboxylate paddlewheel complexes

Gracia, Raquel, Adams, Harry and Patmore, Nathan J. (2009) Relationship between metal–metal bond length and internal rotation in diruthenium tetracarboxylate paddlewheel complexes. Dalton Transactions (2). pp. 259-261. ISSN 1477-9226

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Abstract

The Ru–Ru bond length for Ru2II,III and Ru2II,II paddlewheel complexes containing the bulky carboxylate ligand 2,4,6-triisopropylbenzoate was found to decrease despite a reduction in Ru–Ru bond order, due to increased internal rotation.

Item Type: Article
Subjects: Q Science > Q Science (General)
Q Science > QD Chemistry
Schools: School of Applied Sciences
Depositing User: Sara Taylor
Date Deposited: 03 Oct 2013 09:46
Last Modified: 02 Dec 2016 17:42
URI: http://eprints.hud.ac.uk/id/eprint/18787

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