Jarvis, Ashley N., McLaren, Andrew B., Osborn, Helen M. I. and Sweeney, Joseph B. (2013) Preparation and ring-opening reactions ofN-diphenylphosphinyl vinyl aziridines. Beilstein Journal of Organic Chemistry, 9. pp. 852-859. ISSN 1860-5397
Available under License Creative Commons Attribution.
Predominantly (E)-N-diphenylphosphinyl vinyl aziridines are prepared by a reaction of N-diphenylphosphinyl imines with α-bromoallyllithium in the presence of freshly fused ZnCl2. These aziridines undergo a ring-opening reaction with a variety of carbon and heteronucleophiles, in good yield, and generally with good regioselectivity.
|Uncontrolled Keywords:||aziridines; catalytic; heterocycles; palladium; ring opening|
|Subjects:||Q Science > QD Chemistry|
|Schools:||School of Applied Sciences|
|Depositing User:||Graham Stone|
|Date Deposited:||18 Sep 2013 16:13|
|Last Modified:||04 Nov 2015 18:08|
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