Oxidative Rearrangement of Tertiary Propargylic Alcohols

Tools

Rodríguez, Arantxa and Moran, Wesley J. (2013) Oxidative Rearrangement of Tertiary Propargylic Alcohols. Synlett, 24 (1). pp. 102-104. ISSN 0936-5214

There is a more recent version of this item available.

Metadata only available from this repository.

Official URL: http://dx.doi.org/10.1055/s-0032-1317711

DOI: 10.1055/s-0032-1317711

Abstract

An oxidative rearrangement of tertiary alcohols mediated by m-CPBA is described that generates tetrasubstituted alkenes with a carboxylic acid substituent. The mechanism of the reaction is proposed to proceed through epoxidation of the alkyne to form an oxirene that undergoes a 1,2-aryl shift.

Item Type:	Article
Subjects:	Q Science > QD Chemistry
Schools:	School of Applied Sciences
Related URLs:	Publisher Author
Depositing User:	Wesley Moran
Date Deposited:	06 Dec 2012 15:38
Last Modified:	06 Jun 2013 10:49
URI:	http://eprints.hud.ac.uk/id/eprint/16215

Available Versions of this Item

Oxidative Rearrangement of Tertiary Propargylic Alcohols. (deposited 06 Dec 2012 15:38)[Currently Displayed]
- Oxidative Rearrangement of Tertiary Propargylic Alcohols. (deposited 18 Dec 2012 11:07)

Item control for Repository Staff only:

View Item