Rodríguez, Arantxa and Moran, Wesley J. (2013) Oxidative Rearrangement of Tertiary Propargylic Alcohols. Synlett, 24 (1). pp. 102-104. ISSN 0936-5214Metadata only available from this repository.
An oxidative rearrangement of tertiary alcohols mediated by m-CPBA is described that generates tetrasubstituted alkenes with a carboxylic acid substituent. The mechanism of the reaction is proposed to proceed through epoxidation of the alkyne to form an oxirene that undergoes a 1,2-aryl shift.
|Subjects:||Q Science > QD Chemistry|
|Schools:||School of Applied Sciences|
|Depositing User:||Wesley Moran|
|Date Deposited:||06 Dec 2012 15:38|
|Last Modified:||18 Aug 2016 15:44|
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