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Radical reactions in synthesis: carbon?carbon bond formation from 2-substituted allyl trialkyl stannanes

Baldwin, Jack E., Adlington, Robert M., Birch, David J., Crawford, James A. and Sweeney, Joseph B. (1986) Radical reactions in synthesis: carbon?carbon bond formation from 2-substituted allyl trialkyl stannanes. Journal of the Chemical Society, Chemical Communications (17). p. 1339. ISSN 0022-4936

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Abstract

A competing 1,3-rearrangement of allyl stannanes has been demonstrated to occur under the normal thermal homolytic allyl transfer reaction conditions which limits the substitution patterns in these processes; two methacrylyl stannanes are described which allow the transfer of the methacrylyl moiety to alkyl bromides and iodides under mild conditions

Item Type: Article
Subjects: Q Science > QD Chemistry
Schools: School of Applied Sciences
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Depositing User: Joseph Sweeney
Date Deposited: 09 Oct 2012 10:08
Last Modified: 09 Oct 2012 10:08
URI: http://eprints.hud.ac.uk/id/eprint/15423

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