Enantioselective synthesis of monocerin and fusarentin ethers: Antifungal and insecticidal fungal metabolites.

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Dillon, Michael P., Simpson, Thomas J. and Sweeney, Joseph B. (1992) Enantioselective synthesis of monocerin and fusarentin ethers: Antifungal and insecticidal fungal metabolites. Tetrahedron Letters, 33 (49). pp. 7569-7572. ISSN 0040-4039

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Official URL: http://dx.doi.org/10.1016/S0040-4039(00)60826-2

DOI: 10.1016/S0040-4039(00)60826-2

Abstract

Fusarentin 4,5-dimethyl ether (4) is synthesized via condensation of the benzylic anion of ethyl 3,4,5-trimethoxy-6-methylbenzoate (7) with (S)-3-tetrahydropyranyloxyhexanal (8); subsequent biomimetic cyclisation of (4) gives monocerin (1).

Item Type:	Article
Subjects:	Q Science > QD Chemistry
Schools:	School of Applied Sciences
Related URLs:	Author
Depositing User:	Joseph Sweeney
Date Deposited:	09 Oct 2012 10:42
Last Modified:	09 Oct 2012 10:42
URI:	http://eprints.hud.ac.uk/id/eprint/15417

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