Diastereospecific hydroxyselenation of cyclohex-2-enyl phenylglycinates

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Haughan, Alan F. and Sweeney, Joseph B. (1994) Diastereospecific hydroxyselenation of cyclohex-2-enyl phenylglycinates. Tetrahedron: Asymmetry, 5 (2). pp. 177-180. ISSN 0957-4166

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Official URL: http://dx.doi.org/10.1016/S0957-4166(00)86166-2

DOI: 10.1016/S0957-4166(00)86166-2

Abstract

Cyclohex-2-enyl esters of homochiral (R)-Z-phenylglycine undergo completely regio- and diastereospecific addition reactions with N-phenylselenophthalimide. The resulting selenoalcohols are separable by routine chromatography and may be converted into homochiral 1,3-cyclohexonediols in which the hydroxyl groups are differentiated.

Item Type:	Article
Subjects:	Q Science > QD Chemistry
Schools:	School of Applied Sciences
Related URLs:	Author
Depositing User:	Joseph Sweeney
Date Deposited:	17 Oct 2012 12:58
Last Modified:	17 Oct 2012 12:58
URI:	http://eprints.hud.ac.uk/id/eprint/15412

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