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Diastereospecific hydroxyselenation of cyclohex-2-enyl phenylglycinates

Haughan, Alan F. and Sweeney, Joseph B. (1994) Diastereospecific hydroxyselenation of cyclohex-2-enyl phenylglycinates. Tetrahedron: Asymmetry, 5 (2). pp. 177-180. ISSN 0957-4166

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Abstract

Cyclohex-2-enyl esters of homochiral (R)-Z-phenylglycine undergo completely regio- and diastereospecific addition reactions with N-phenylselenophthalimide. The resulting selenoalcohols are separable by routine chromatography and may be converted into homochiral 1,3-cyclohexonediols in which the hydroxyl groups are differentiated.

Item Type: Article
Subjects: Q Science > QD Chemistry
Schools: School of Applied Sciences
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Depositing User: Joseph Sweeney
Date Deposited: 17 Oct 2012 12:58
Last Modified: 17 Oct 2012 12:58
URI: http://eprints.hud.ac.uk/id/eprint/15412

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