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Preparation and ring-opening reactions of N-diphenylphosphinyl vinyl aziridines

Cantrill, Alexander, Jarvis, Ashley, Osborn, Helen, Ouadi, Ali and Sweeney, Joseph B. (1996) Preparation and ring-opening reactions of N-diphenylphosphinyl vinyl aziridines. Synlett, 9. pp. 847-849. ISSN 0936-5214

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Abstract

N-Diphenylphosphinyl-3-ethenyl-2-phenylaziridine (1) and N-diphenylphosphinyl-3-ethenyl-2-(4-bromophenyl)aziridine (2) are prepared by reaction of α-bromo allyllithium with N-diphenylphosphinyl aldimines in the presence of zinc chloride. (1) and (2) undergo efficient SN2' ring-opening reaction with several nucleophiles.

Item Type: Article
Subjects: Q Science > QD Chemistry
Schools: School of Applied Sciences
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Depositing User: Joseph Sweeney
Date Deposited: 17 Oct 2012 13:57
Last Modified: 17 Oct 2012 13:57
URI: http://eprints.hud.ac.uk/id/eprint/15397

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