Search:
Computing and Library Services - delivering an inspiring information environment

Asymmetric aziridine synthesis via aza-Darzens reaction of bromoacylcamphorsultam

Cantrill, Alex A., Hall, Lee D., Jarvis, Ashley N., Osborn, Helen M. I., Raphy, Jenny and Sweeney, Joseph B. (1996) Asymmetric aziridine synthesis via aza-Darzens reaction of bromoacylcamphorsultam. Chemical Communications (23). p. 2631. ISSN 1359-7345

Metadata only available from this repository.

Abstract

The aza-Darzens reaction of the chiral enolate derived from bromoacetylcamphorsultam 1 with N-(diphenyl-phosphinyl)aryl- and tert-butyl-methanimines proceeds in good yield to give cis-N-(diphenylphosphinyl)aziridinylcarbonyl sultams with high de. Monochiral cis-aziridinecarboxylates may be obtained in acceptable yield by hydrolysis of these sultams.

Item Type: Article
Subjects: Q Science > QD Chemistry
Schools: School of Applied Sciences
Related URLs:
Depositing User: Joseph Sweeney
Date Deposited: 17 Oct 2012 14:01
Last Modified: 17 Oct 2012 14:01
URI: http://eprints.hud.ac.uk/id/eprint/15395

Item control for Repository Staff only:

View Item

University of Huddersfield, Queensgate, Huddersfield, HD1 3DH Copyright and Disclaimer All rights reserved ©