Stannylfuranones in synthesis: Highly enantioselective preparation of (+)-hamabiwalactone B

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Richecoeur, Alexandre M.E. and Sweeney, Joseph B. (1998) Stannylfuranones in synthesis: Highly enantioselective preparation of (+)-hamabiwalactone B. Tetrahedron Letters, 39 (48). pp. 8901-8904. ISSN 0040-4039

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Official URL: http://dx.doi.org/10.1016/S0040-4039(98)01946-7

DOI: 10.1016/S0040-4039(98)01946-7

Abstract

An unambiguous and highly enantioselective total synthesis of the naturally-occurring 2(5H)-furanone hamabiwalactone B has been achieved. The key step is a Stille coupling of novel stannylfuranone2 with (E)-iodoalkene3. The enantiomeric purity of the synthetic natural product was ≥99%, as judged by chiral HPLC.

Item Type:	Article
Subjects:	Q Science > QD Chemistry
Schools:	School of Applied Sciences
Related URLs:	Author
Depositing User:	Joseph Sweeney
Date Deposited:	18 Oct 2012 11:16
Last Modified:	18 Oct 2012 11:16
URI:	http://eprints.hud.ac.uk/id/eprint/15303

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