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Richecœur, Alexandre M.E. and Sweeney, Joseph B. (2000) Preparation of (+)-Hamabiwalactone B via Stille Coupling of an Enantiomerically Pure Stannylfuranone. Tetrahedron, 56 (3). pp. 389-395. ISSN 0040-4020
Metadata only available from this repository.Official URL: http://dx.doi.org/10.1016/S0040-4020(99)00998-9
Abstract
An unambiguous and highly enantioselective total synthesis of the naturally occurring 2(5H)-furanone Hamabiwalactone B has been achieved. The key step was a palladium-catalysed cross coupling (“Stille” coupling) of the previously unreported stannylfuranone 2 with (E)-iodoalkene 3. The enantiomeric purity of the synthetic natural product was ≥99%, as judged by chiral HPLC.
| Item Type: | Article |
|---|---|
| Subjects: | Q Science > QD Chemistry |
| Schools: | School of Applied Sciences |
| Related URLs: | |
| Depositing User: | Joseph Sweeney |
| Date Deposited: | 18 Oct 2012 11:25 |
| Last Modified: | 18 Oct 2012 11:25 |
| URI: | http://eprints.hud.ac.uk/id/eprint/15292 |
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