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Aziridines: epoxides' ugly cousins?

Sweeney, Joseph B. (2002) Aziridines: epoxides' ugly cousins? Chemical Society Review, 31 (5). pp. 247-258. ISSN 0306-0012

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Abstract

Aziridines, the nitrogenous analogues of epoxides, have until recently excited far less interest amongst synthetic organic chemists than their oxygenated counterparts, with some justification. A range of reviews concerned with the physical properties, synthesis (asymmetric and otherwise), reactions and utility of aziridines exists; this review briefly summarizes the similarities and differences between oxiranes and their nitrogenated analogues, concentrating on the underlying properties of aziridines and recent developments in their chemistry. In addition to descriptions of the physical nature of aziridines, especially those features which underpin their utility as synthetic intermediates, the sections beneath describe reactions involving alkylative ring-opening and synthesis of aziridines.

Item Type: Article
Subjects: Q Science > QD Chemistry
Schools: School of Applied Sciences
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Depositing User: Joseph Sweeney
Date Deposited: 18 Oct 2012 11:34
Last Modified: 18 Oct 2012 11:34
URI: http://eprints.hud.ac.uk/id/eprint/15284

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