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Preparation and ring-opening reactions of N,O-bis(diphenylphosphinyl) hydroxymethylaziridine (‘Di-Dpp’)

Sweeney, Joseph B. and Cantrill, Alex A (2003) Preparation and ring-opening reactions of N,O-bis(diphenylphosphinyl) hydroxymethylaziridine (‘Di-Dpp’). Tetrahedron, 59 (21). pp. 3677-3690. ISSN 0040-4020

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Abstract

N,O-bis(diphenylphosphinyl)-2-(hydroxymethyl)aziridine (‘DiDpp’, 1) is efficiently prepared from 2-aminoethane-1,3-diol: this activated aziridine undergoes two sequential reactions with copper(I)-modified Grignard reagents, yielding α-branched N-Dpp amines in good yield.

Item Type: Article
Subjects: Q Science > QD Chemistry
Schools: School of Applied Sciences
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Depositing User: Joseph Sweeney
Date Deposited: 18 Oct 2012 12:00
Last Modified: 18 Oct 2012 12:00
URI: http://eprints.hud.ac.uk/id/eprint/15234

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