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Luminescent rhenium fac-tricarbonyl-containing complexes of androgenic oxo-steroids

Bullock, Sam, Hallett, Andrew J., Harding, Lindsay P., Higginson, Joshua J., Piela, Sean A.F., Pope, Simon J.A. and Rice, Craig R. (2012) Luminescent rhenium fac-tricarbonyl-containing complexes of androgenic oxo-steroids. Dalton Transactions. ISSN 14779226

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    Abstract

    A new route to luminescent derivatives of androgenic steroids containing a ketone group in the 3-
    or 17-position has been developed. Reaction with the fac-Re(CO)3Cl complex of 3,3’-diamino-2,2’-
    bipyridine (complex 1) afforded a cyclic aminal product with different steroids. The rate of reaction
    and yield varies according to the conjugation or steric hindrance around the ketone group

    Item Type: Article
    Subjects: Q Science > QD Chemistry
    Schools: School of Applied Sciences
    Related URLs:
    Depositing User: Lindsay Harding
    Date Deposited: 09 Oct 2012 15:18
    Last Modified: 27 Sep 2013 01:38
    URI: http://eprints.hud.ac.uk/id/eprint/15205

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