Bullock, Sam, Hallett, Andrew J., Harding, Lindsay P., Higginson, Joshua J., Piela, Sean A.F., Pope, Simon J.A. and Rice, Craig R. (2012) Luminescent rhenium fac-tricarbonyl-containing complexes of androgenic oxo-steroids. Dalton Transactions. ISSN 14779226
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A new route to luminescent derivatives of androgenic steroids containing a ketone group in the 3-
or 17-position has been developed. Reaction with the fac-Re(CO)3Cl complex of 3,3’-diamino-2,2’-
bipyridine (complex 1) afforded a cyclic aminal product with different steroids. The rate of reaction
and yield varies according to the conjugation or steric hindrance around the ketone group
|Subjects:||Q Science > QD Chemistry|
|Schools:||School of Applied Sciences|
|Depositing User:||Lindsay Harding|
|Date Deposited:||09 Oct 2012 15:18|
|Last Modified:||10 Oct 2012 14:37|
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