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Bullock, Sam, Hallett, Andrew J., Harding, Lindsay P., Higginson, Joshua J., Piela, Sean A.F., Pope, Simon J.A. and Rice, Craig R. (2012) Luminescent rhenium fac-tricarbonyl-containing complexes of androgenic oxo-steroids. Dalton Transactions. ISSN 14779226
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Official URL: http://dx.doi.org/10.1039/C2DT31476B
DOI: 10.1039/C2DT31476B
Abstract
A new route to luminescent derivatives of androgenic steroids containing a ketone group in the 3-
or 17-position has been developed. Reaction with the fac-Re(CO)3Cl complex of 3,3’-diamino-2,2’-
bipyridine (complex 1) afforded a cyclic aminal product with different steroids. The rate of reaction
and yield varies according to the conjugation or steric hindrance around the ketone group
| Item Type: | Article |
|---|---|
| Subjects: | Q Science > QD Chemistry |
| Schools: | School of Applied Sciences |
| Related URLs: | |
| Depositing User: | Lindsay Harding |
| Date Deposited: | 09 Oct 2012 15:18 |
| Last Modified: | 10 Oct 2012 14:37 |
| URI: | http://eprints.hud.ac.uk/id/eprint/15205 |
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