Structural studies of a novel heterocyclic phosphorane

Tools

Gabbutt, Christopher D., Hepworth, John D., Heron, B. Mark, Jones, Alan M., Raper, Eric S. and Clegg, William (1998) Structural studies of a novel heterocyclic phosphorane. Phosphorus, Sulfur, and Silicon and the Related Elements, 143 (1). pp. 221-230. ISSN 1042-6507

Metadata only available from this repository.

Official URL: http://dx.doi.org/10.1080/10426509808045499

DOI: 10.1080/10426509808045499

Abstract

Reaction of 2,2,6-trimethylthiochroman-3,4-dione with an excess of methylenetriphenylphosphorane yields the stabilised ylide (4) by way of an α-ketol rearrangement. X-Ray crystallography indicates that (4) exists as the (a-isomer and provides supporting evidence for an enolate structure.

Item Type:	Article
Subjects:	Q Science > Q Science (General) Q Science > QD Chemistry
Schools:	School of Applied Sciences
Related URLs:	Author Author
Depositing User:	Sharon Beastall
Date Deposited:	20 Sep 2012 13:45
Last Modified:	18 Oct 2012 10:51
URI:	http://eprints.hud.ac.uk/id/eprint/14995

Item control for Repository Staff only:

View Item