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Structural studies of a novel heterocyclic phosphorane

Gabbutt, Christopher D., Hepworth, John D., Heron, B. Mark, Jones, Alan M., Raper, Eric S. and Clegg, William (1998) Structural studies of a novel heterocyclic phosphorane. Phosphorus, Sulfur, and Silicon and the Related Elements, 143 (1). pp. 221-230. ISSN 1042-6507

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Abstract

Reaction of 2,2,6-trimethylthiochroman-3,4-dione with an excess of methylenetriphenylphosphorane yields the stabilised ylide (4) by way of an α-ketol rearrangement. X-Ray crystallography indicates that (4) exists as the (a-isomer and provides supporting evidence for an enolate structure.

Item Type: Article
Subjects: Q Science > Q Science (General)
Q Science > QD Chemistry
Schools: School of Applied Sciences
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Depositing User: Sharon Beastall
Date Deposited: 20 Sep 2012 13:45
Last Modified: 18 Oct 2012 10:51
URI: http://eprints.hud.ac.uk/id/eprint/14995

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