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Gill, Duncan M., Dyke, Alan, Harvey, Jeremy, Hester, Alison, Lloyd-Jones, Guy, Paz Munoz, Maria and Sheperson, Ian (2008) Decoupling Deprotonation from Metalation: Thia-Fries Rearrangement. Angewandte Chemie International Edition, 47 (27). pp. 5067-5070. ISSN 14337851
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Official URL: http://dx.doi.org/10.1002/anie.200800750
Abstract
Label-enabled: Studies with 2H-, 18O-, and 34S-labeled aryl triflates show that lithium diisopropylamide-mediated thia-Fries rearrangement proceeds through an irreversible ortho deprotonation (see scheme; DIPA=diisopropylamine, LDA=lithium diisopropylamide). In contrast, ortho metalation results exclusively in the generation of a benzyne.
| Item Type: | Article |
|---|---|
| Subjects: | Q Science > QD Chemistry |
| Schools: | School of Applied Sciences |
| Depositing User: | Duncan Gill |
| Date Deposited: | 27 Sep 2012 12:27 |
| Last Modified: | 17 Oct 2012 12:07 |
| URI: | http://eprints.hud.ac.uk/id/eprint/14876 |
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