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Gill, Duncan M. (2012) Stereoselective synthesis of a dialkylhydantoin featuring an asymmetric Strecker reaction on an acyclic dialkyl ketone. Tetrahedron Letters, 53 (15). pp. 1951-1953. ISSN 0040-4039
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Official URL: http://dx.doi.org/10.1016/j.tetlet.2012.02.008
Abstract
A diastereoselective Strecker reaction using (R)-(-)-phenylglycinol forms the basis of a concise scalemic route to dialkylhydantoin 1. The phenylglycinol functionality was exploited in the manipulation of the aminonitrile Strecker product through to the dialkylhydantoin via a short, efficient sequence involving crystalline intermediates.
| Item Type: | Article |
|---|---|
| Subjects: | Q Science > QD Chemistry |
| Schools: | School of Applied Sciences |
| Depositing User: | Duncan Gill |
| Date Deposited: | 07 Jun 2012 10:16 |
| Last Modified: | 17 Oct 2012 11:59 |
| URI: | http://eprints.hud.ac.uk/id/eprint/13698 |
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