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Chiral Aryl Iodide-Catalyzed Enantioselective α-Oxidation of Ketones

Rodríguez, Arantxa and Moran, Wesley J. (2012) Chiral Aryl Iodide-Catalyzed Enantioselective α-Oxidation of Ketones. Synthesis, 44 (8). pp. 1178-1182. ISSN 00397881

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Abstract

Several chiral aryl iodides were synthesized and assessed as catalysts in the enantioselective α-oxytosylation of propiophenone and the oxidative cyclization of 5-oxo-5-phenylpentanoic acid to 5-benzoyldihydrofuran-2(3H)-one. The highest enantioselectivities obtained were 18 and 51% ee, respectively. The latter is the highest selectivity recorded to date for this reaction.

Item Type: Article
Subjects: Q Science > Q Science (General)
Q Science > QD Chemistry
Schools: School of Applied Sciences
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Depositing User: Sara Taylor
Date Deposited: 17 Apr 2012 16:17
Last Modified: 26 Jun 2012 11:07
URI: http://eprints.hud.ac.uk/id/eprint/13308

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