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Iodobenzene-Catalyzed Intramolecular Oxidative Cyclization Reactions of δ-Alkynyl β-Ketoesters

Rodriguez, Arantxa and Moran, Wesley J. (2011) Iodobenzene-Catalyzed Intramolecular Oxidative Cyclization Reactions of δ-Alkynyl β-Ketoesters. Organic Letters, 13 (9). pp. 2220-2223. ISSN 15237060

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Abstract

Iodobenzene is shown to catalyze the 5-exo-dig cyclization of δ-alkynyl β-ketoesters under oxidative conditions that generate hypervalent iodine species in situ. The cyclopentane products contain adjacent quaternary and tertiary stereocenters which are generated with excellent diastereoselectivity.

Item Type: Article
Subjects: Q Science > QD Chemistry
Schools: School of Applied Sciences
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Depositing User: Graham Stone
Date Deposited: 11 Apr 2011 12:40
Last Modified: 18 May 2011 08:52
URI: http://eprints.hud.ac.uk/id/eprint/10097

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